MS Report from Instrument: LCMS-03 File ..\\Data\\20180104\\20180104\\CPK2018-103-09867.D Tgt Mass (CHM): Injection Date : 4 Jan 18 6:13 pm +0800 Seq. Line : 104 Sample Name : CPK2018-103-09867 Location : P2-C-01 Acq. Operator : SYSTEM Inj : 1 Spec. Reported : MS Integration Inj Volume : 2 ul Acq. Method : D:\\LCMS03\\Data\\20180104\\20180104\\1-POS-3MIN.M Analysis Method : D:\\LCMS03\\Data\\20180104\\20180104\\1-POS-3MIN.M Catalog No : HY-16228 Batch#09867 Method Info : Mobile Phase: A: water(0.01%TFA) B:ACN(0.01%TFA) Gradient: 5% to 95%B within 1.3 min Flow Rate :1.8ml/min Column :SunFire C18, 4.6*50mm,3.5um A-RP-186 Oven Temperature : 45C DAD1 A, Sig=214,4 Ref=off1.1981.2971.327mAU200000.5 DAD1 B, Sig=254,4 Ref=offmAU500000.5 ELS1 A, ELSD SignalmV5000.51 MSD1 TIC, MS File ES-API, Pos, Scan, Frag: 701000000500000000.511.5 Ion 408.4, MSD1 408.4,Target Mass 407.4 +H Positive, EIC=408.1:409.1600000400000200000000.51 Integration Results for DAD1 A, Sig=214,4 Ref=off1.23022.5min1.2311.522.5min11.26711.1981.3961.4251.4561.5632.0311.522.5min1.2961.3281.3971.4231.4541.5652.0331.522.5min1.522.5min RetTim Width Area Height Area% MS(+)|-------|--------|--------------|--------------|--------|------| 1.20 0.02 575.63 421.95 98.00 408 1.30 0.01 0.40 0.49 0.07 408 1.33 0.02 6.33 5.25 1.08 408 1.40 0.01 2.11 2.40 0.36 702 1.42 0.01 0.45 0.58 0.08 505 1.46 0.02 0.84 0.15 0.14 447 1.56 0.02 1.34 0.91 0.23 233 2.03 0.02 0.28 0.26 0.05 105 Integration Results for DAD1 B, Sig=254,4 Ref=off RetTim Width Area Height Area% MS(+)|-------|--------|--------------|--------------|--------|------| 1.20 0.02 1340.71 995.85 98.42 408 1.30 0.01 0.35 0.49 0.03 408 1.33 0.02 12.16 9.68 0.89 589 1.40 0.02 5.05 5.36 0.37 702 1.42 0.01 0.99 1.13 0.07 505 1.45 0.02 0.89 -0.00 0.07 447LCMS-03 1/5/2018 10:22:36 AM SYSTEMPage1 of4MS Report from Instrument: LCMS-03 1.57 0.02 0.95 0.87 0.07 233 2.03 0.02 1.20 1.14 0.09 105 Integration Results for MSD1 TIC, MS File RetTim Width Area Height Area% MS(+)|-------|--------|--------------|--------------|--------|------| 1.23 0.06 5279891.00 1387770.88 100.00 408LCMS-03 1/5/2018 10:22:36 AM SYSTEMPage2 of4MS Report from Instrument: LCMS-03Ret. Time: 1.23 <<<< POSITIVE SPECTRA >>>> ES-API Positive408.2204.6189.1409.22500002000001500001000000100200300400500600700800900m/z838.350000LCMS-03 1/5/2018 10:22:36 AM SYSTEMPage3 of4MS Report from Instrument: LCMS-03 *** End of Report ***LCMS-03 1/5/2018 10:22:36 AM SYSTEMPage4 of4